http://weeping00willow.livejournal.com/ ([identity profile] weeping00willow.livejournal.com) wrote in [community profile] spnstoryfinders on January 8th, 2012 at 04:39 pm
I don't know if this is what you're looking for, but it's the first thing that pops into my mind reading your request:

"One going on eternity and counting" by leonidaslion:
http://archiveofourown.org/works/181640/chapters/267129

Sam is in love with Dean and when they have sex for the first time, Sam doesn't notice that Dean doesn't actually enjoy it, that he only agreed to it because Sam wanted it. And things go downhill from there.
 
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